新型硫代双烯镍络合物合成及其对菁染料的光稳定作用

在合成中间体二(4-叔丁基苯基)羟乙酮基础上,进一步合成了双(1,2-二(4-叔丁基苯基)-1,2-二硫代双烯)镍络合物(DYE-02),利用核磁共振氢谱、红外光谱和元素分析等方法对中间体及DYE-02的结构进行了表征,并研究了DYE-02自身的光稳定性能及其对菁染料(Cy7)的光稳定作用.结果表明,与双(1,2-二苯基-1,2-二硫代双烯)镍络合物(DYE-01)相比,苯环上引入叔丁基后,DYE-02的最大近红外吸收波长在885nm,发生明显的红移,具备更好的自身光稳定性,并且能明显提高菁染料的光稳定性.     

烟草生产储存火灾危险性及防火对策研究

通过分析烟草生产、储存中的火灾危险性和当前烟草生产、储存时采用的防火措施，对卷烟联合生产工房内储存物料的安全间距、厂房和仓库外搭建雨篷、消防车道和烟草仓库消防设施设计等问题进行了探讨。     

基于复杂网络的装备保障网络结构脆弱性分析

通过网络化实现装备保障一体化是装备保障体系建设的重点问题。在分析复杂网络脆弱性基本理论的基础上,通过定义装备保障网络中节点、边,构建了典型的装备保障网络拓扑结构模型,提出了装备保障网络的随机失效和蓄意攻击失效两种失效模式,并对两种失效模式下不同装备保障网络的结构脆弱性进行了仿真分析,为装备保障网络的构建以及防护策略的制定提供了科学的参考依据。研究结果表明:从防御角度而言,适当增加不同保障实体之间的交叉连接有助于提高装备保障网络的抗毁性;而从攻击角度而言,二次攻击则可有效提高攻击效率,以达到迅速瘫痪装备保障体系的目的。     

地下储油复杂组合空间油气扩散蔓延三维数值模拟

针对地下储油复杂组合空间,采用大涡模拟的方法构建了油气扩散蔓延三维数值模拟模型,完成了油气扩散蔓延区域的空间离散和三维数值模拟求解优化,并进行了数值计算与分析。结果表明,在地下复杂组合受限空间油料泄漏后,罐室内的油气填充顺序为由边缘到出口、由底部到上部,油气不能达到100%的充满状态,罐室拱形顶部油气体积分数低于其爆炸下限的20%;罐室内油气的产生和蔓延十分迅速,从泄漏至到达罐室口仅需10 s,进入坑道仅需1 min;油气在流出罐室进入坑道后,具有迅速向四周扩散蔓延,流向一切可能注入的空间的特性。研究结果为地下储油工程的施工建设、安全管理、危险源监控等提供了有益参考。     

KL散度多模块滑动窗口慢特征分析的故障诊断方法

针对传统分块方法根据经验划分子块导致变量特征信息无法充分利用,其单一的建模方式忽略局部信息以及离线模型无法适应时变特性的问题,提出了一种KL (Kullback-Leibler)散度多模块滑动窗口慢特征分析方法。在正常工况数据集中,利用KL散度来度量变量间的距离,同时引入最小误差平方和准则进行聚类,分成两个距离最小的子模块;在此基础上利用慢特征分析方法对每个子模块进行建模,结合滑动窗口对每次采样的数据进行更新,得到最优模型,分别计算监测统计信息,利用支持向量数据描述对故障监测结果进行融合,实现故障诊断。并将该方法应用于田纳西伊斯曼过程的监控中,得到了较高的故障检测率和较低的虚警率,验证了该方法的可行性和有效性。     

弯曲致受抑全内反射式液位检测效应仿真实验分析

从传统的有损光纤结构的液位传感方法入手,深入研究塑料多模光纤传输过程中的包层模式下的弯曲损耗、受抑全内反射以及光能量耦合机理,在理论上揭示传感器效应的作用机制,从几何光学的理论出发,使用光线追迹方法,进一步模拟宏弯曲光纤内的光线传播路径,光纤受抑全内反射效应的能量变化机制,仿真结果与理论分析一致,搭建实验平台对前述理论分析和仿真模拟结果进行进一步的测试和验证。实验结果表明,该效应相对于传统有损光纤结构方法,可以进行高精度高灵敏度的稳定可靠液位传感测量。     

协同作战中信息分发算法研究

大规模协同作战中的高效通信问题为当前信息战的研究重点之一,但由于单独作战单元无法了解全局的信息内容及需求方,这给通信资源有限的参战兵力之间的态势共享带来了困难。为此提出了一个分布式协作信息分发算法,在理论上借鉴了复杂网络的小世界特性,即单元节点可以通过邻节点在较少跳数内完成信息的传输。在思路上利用了信息相关性概念,作战单元利用信息之间的关联性及信息与节点之间的收发关系建立控制信息发送的路由表。并通过仿真实验验证了不同网络拓扑下算法性能的变化情况,结果证明分发算法能较好地支持信息共享。     

基于复杂排队系统的三值光学计算机服务模型与性能分析

三值光学计算机的运算请求处理过程缺乏合理、系统的性能评价标准与体系。基于M/M/1、M/M/n、M~X/M/1和M/M~B/1构成的复杂排队系统,构建三值光学计算机的四阶段服务模型,同时建立立即调度和结束时调度两种策略和算法。基于不同排队系统讨论运算请求的接收时间、预处理时间、运算时间和发送时间的计算方法,进而得到最终响应时间。通过仿真实验对两种策略的模型进行验证,结果表明,结束时调度策略明显优于立即调度策略。     

A study on the surface overpressure distribution and formation of a double curvature liner under a two-point initiation

The formation mechanism of an EFP(explosively formed projectile) using a double curvature liner under the overpressure effect generated by a regular oblique reflection was investigated in this paper.Based on the detonation wave propagation theory,the change of the incident angle of the detonation wave collision at different positions and the distribution area of the overpressure on the surface of the liner were calculated.Three-dimensional numerical simulations of the formation process of the EFP with tail as well as the ability to penetrate 45# steel were performed using LS-DYNA software,and the EFP ve-locity,the penetration ability,and the forming were assessed via experiments and x-ray photographs.The experimental results coincides with those of the simulations.Results indicate that the collision of the detonation wave was controlled to be a regular oblique reflection acting on the liner by setting the di-mensions of the unit charge and maintaining the pressure at the collision point region at more than 2.4 times the CJ detonation when the incident angle approached the critical angle.The distance from the liner midline to the boundary of the area within which the pressure ratio of the regular oblique reflection pressure to the CJ detonation pressure was greater than 2.5,2,and 1.5was approximately 0.66 mm,1.32 mm,and 3.3 mm,respectively.It is noted that pressure gradient caused the liner to turn inside out in the middle to form the head of the EFP and close the two tails of the EFP at approximately 120μs.The penetration depth of the EFP into a 45# steel target exceeded 30 mm,and there was radial expansion between the head and tail of the EFE increasing the penetration resistance of the EFP.Therefore,the structural size of the unit charge and the liner can be further optimized to reduce resistance to increase the penetration ability of the EFP.     

Driving force coordinated control of an 8 ×8 in-wheel motor drive vehicle with tire-road friction coefficient identification

Because of the complexities of tire-road interaction,the wheels of a multi-wheel distributed electric drive vehicle can easily slip under certain working conditions.As wheel slip affects the dynamic per-formance and stability of the vehicle,it is crucial to control it and coordinate the driving force.With this aim,this paper presents a driving force coordination control strategy with road identification for eight-wheeled electric vehicles equipped with an in-wheel motor for each wheel.In the proposed control strategy,the road identification module estimates tire-road forces using an unscented Kalman filter al-gorithm and recognizes the road adhesion coefficient by employing the recursive least-square method.According to road identification,the optimal slip ratio under the current driving condition is obtained,and a controller based on sliding mode control with a conditional integrator uses this value for accel-eration slip regulation.The anti-slip controller obtains the adjusting torque,which is integrated with the driver-command-based feedforward control torque to implement driving force coordination control.The results of hardware-in-loop simulation show that this control strategy can accurately estimate tire-road forces as well as the friction coefficient,and thus,can effectively fulfill the purpose of driving force coordinated control under different driving conditions.